Research & Development
Mobil Refines Coal-Derived Oil
Friday, 08/27/2010
 
We have frequently made reference to the Fischer-Tropsch technology for converting Coal into liquid hydrocarbons. Although it is only one of the technologies which enable such conversion of Coal, it seems to be the one most studied and most developed.
 
A drawback of the Fischer-Tropsch process lies in the types of liquid hydrocarbons that are catalytically condensed out of the synthesis gas generated from the original Coal.
 
Raw Fischer-Tropsch condensate can contain a lot of high-molecular-weight oils that are deficient in Hydrogen content, and which are not volatile enough to be used, as is, for fuels.
 
The oil industry knows all of that, and, as we have earlier documented, has devoted some effort into the development of refining techniques for Coal-derived liquids, in order to more efficiently make typical liquid hydrocarbon fuels out of those Coal liquids - just as they had to devote effort into doing the same thing with crude petroleum oil.
 
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Shel Oil CO2 + CH4 + H2O = Kerosene
Friday, 08/27/2010
 
We have many times documented the existence of technologies wherein Carbon Dioxide can be reacted, "reformed", with Methane, leading to the synthesis of higher hydrocarbons.
 
Keep in mind that, as affirmed recently by NASA, in their published plans for making rocket fuel on the planet Mars, as documented in our reports, that Methane can itself be synthesized from Carbon Dioxide via the "Sabatier" process, which won the Nobel Prize in Chemistry for it's inventor all the way back in 1912.
 
Herein, we see that Shell Oil, with contributions from Shell scientists in both the Netherlands and Texas, developed their own process for reacting Carbon Dioxide with Methane, in order to synthesize higher hydrocarbons.
 
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Mobil Co-Liquefies Coal & CO2-Recycling Wastes
Thursday, 08/26/2010
 
We have noted, in the course of our reportage, that technologies for the conversion of Coal into liquid and gaseous hydrocarbons, suitable as direct replacements for those we now derive from petroleum, can be adapted so that Carbon-recycling and renewable organic materials of biologic origin can be included in the raw material feed.
 
Inclusion and use of such products not only recycles environmental Carbon, and offers the potential for profitable use of what might otherwise be waste materials, but also introduces an element of sustainability.
 
Mobil Oil Corporation, whose Coal conversion expertise we have extensively documented, spells all of that out quite clearly in the United States Patent we enclose herein.
 
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Texaco Improves Coal Hydrogasification
Thursday, 08/26/2010
  
We have extensively documented the Coal gasification conversion expertise of the former Texaco, now a component of Chevron.
 
Since, in a very recent report, we documented that the United States Environmental Protection Agency had utilized a Texaco Coal Gasification facility to, in the process of gasifying Pittsburgh Seam Coal, clean up and convert into hydrocarbon synthesis gas the toxic wastes left by a California petroleum refinery, we thought it timely to submit this report of their advanced technology for, as they put it, improving "the economy and efficiency of ... producing large volumes of synthesis gas comprising principally hydrogen and carbon monoxide", from a variety of organic substances.
 
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Shell Oil Coal + Steam = Hydrocarbons
Wednesday, 08/25/2010
 

This Shell Oil technology is mostly about the processing of synthesis gas, once it is produced from Coal, in order to generate more versatile, and more valuable, hydrocarbons.
 
We submit it only to emphasize, yet again, that hydrogenated synthesis gas suitable for efficient catalytic conversion into more useful hydrocarbons can be readily produced via the Steam gasification of Coal.
 
That fact is highlighted in the following passage excerpted from the main body of the Disclosure, where it is included almost as an isolated aside:
 
"In the process according to the invention the starting material is an H2/CO mixture with an H2/CO molar ratio of less than 1.0. Such H2/CO mixtures can very suitably be prepared by steam gasification of a carbon containing material. Examples of such materials are brown coal, anthracite ... ."
 
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